Morphological and Structural Marks of Secondary Phases Formation in GdSr2RuCu2O8-d Melting Process

Author: Gombos, Marcello

Affiliation: CNR-ISASI

Type: Poster

Display Dates: 22.07.2026 - 23.07.2026

Board: WT-113

GdSr2RuCu2O8-d (Gd1212) is known to show both superconducting and magnetic ordered phases coexisting in the same cell. To study these unconventional features, macroscopic crystallographically oriented samples are needed. But Gd1212 synthesis and the fabrication of high-quality samples are intrinsically difficult, so the most effective way to achieve the best properties (even due to the unavailability of single crystals) appears to be via melt texturing techniques. A better understanding of melting reaction is then needed.

A study of Gd1212 melting process was performed, by preparing a series of pellets annealed each at a different temperature, below and above the melting temperature. XRD, TG-DTA, and SEM characterisations, supplemented by EDS analysis, revealed the presence of different phases, corresponding to those identified in our previous studies; their formation shows a strong dependence on the treatment temperature. These observations were also confirmed by Raman Microscopy and Mapping performed on molten and re-solidified samples.