Kagome metals AV₃Sb₅ (where A = Cs, K, Rb) have a complex electronic structure comprising flat bands, Dirac crossings and van Hove singularities. In CsV₃Sb₅, the CDW transition has been associated with time-reversal symmetry breaking, orbital magnetism, and chirality. This talk summarises x-ray photoelectron diffraction (XPD) and angle-resolved photoemission spectroscopy (ARPES) studies of this system using circularly polarised photons. XPD reveals a loss of mirror symmetry and the formation of a locally chiral atomic structure in the CDW phase. Complementary ARPES measurements reveal pronounced nontrivial magnetic circular dichroism (MCD) in the valence-band electronic structure, suggesting the presence of electronic chirality and time-reversal symmetry breaking. Partially substituting V atoms with the isoelectronic Nb atoms results in band broadening and increased gap opening at the Dirac-like crossings due to the resulting chemical pressure. Isoelectronic Nb substitution also results in stronger coupling of orbital magnetic moments to three van Hove singularities near the Fermi level at the M points. This enhances the MCD signal compared to pristine CsV₃Sb₅.